December 14 2024 by Sadie Daniel Officials said the 77 acre 31 hectare reservoir holds millions of gallons of water containing phosphorus and nitrogen from an old phosphate plant The pond where the leak was found is in a stack of phosphogypsum a radioactive waste product from the manufacture of fertiliser Contents
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Get PricePhosphogypsum is a side product obtained from the production of phosphoric acid by treating phosphate ore apatite with sulfuric acid It is primarily composed of gypsum CaSO4·2H2O Gypsum is a widely used material in the building construction industry however phosphogypsum is usually not utilized in building construction
Get Pricephosphogypsum is classified as TENORM Technologically Enhanced Naturally Occurring Radioactive Material that is a solid waste containing naturally occurring radioactive elements from the rock matrix Environmental impact studies should assess the existing site and conditions and evaluate the anticipated impacts on the environment itself by
Get PricePhosphogypsum is a by product from the production of phosphoric acid by treating phosphate ore apatite with sulfuric acid according to the following reaction Ca 5 PO 4 3 X 5 H 2 SO 4 10 H 2 O → 3 H 3 PO 4 5 CaSO 4 · 2 H 2 O HX where X may include OH F Cl or Br
Get PriceThe overall results proved that in treated phosphogypsum based cemented paste backfill TCPB the altered particle size distribution can alleviate the shear thinning characteristic The mechanical properties were significantly optimized of which a maximum increase of 183% of stress value was observed
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Get PriceThe byproduct phosphogypsum can be purified by treating with 3 4% aqueous citric acid solution and subsequent washing with water 2 The impurities of phosphates and fluorides are removed as water soluble phosphoric acid sodium citrate hydrofluoric acid hydrofluorosilicate hydrofluoroaluminate and ferrate 3
Get PriceThe phosphogypsum used during this work comes from the waste of the preparation of phosphoric acid in the complex Maroc phosphore settled at Jorf Lasfar near El Jadida It undergoes a lot of washes to eliminate the residual acidity the salts and the suspension material which floats on the surface of the washing water organic matter
Get PriceThe reduction of SO 3 concentration in phosphogypsum after washing with calcium hydroxide The presence of SO 3 Sr Ti and Ni in the treated phosphogypsum is presented in figures 10 11 12 and 13 respectively The percentage of SO 3 was reduced by 7% for washing one time and 9% after washing three times based on its measured values Figure 10
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Get PriceHigh amounts of phosphogypsum PG are generated in the production of phosphoric acid Previous literature demonstrates that obtaining rare earth elements REE from PG is a promising alternative to managing this waste However the reported leaching efficiencies are low in most cases or drastic le …
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Get PriceThe treated wastewater may be for floor wash gardening/irrigation purpose or disposed Gypsum is mainly used by sulphuric acid manufacturing industry in the form of phosphogypsum byproduct of gypsum is used in manufacture of cements partition blocks sheets
Get PriceThe second portion of the leaching solution is taken for sorption extraction of rare earth elements using a sulphoxide cationite to obtain a lean sulphuric acid solution After leaching the phosphogypsum is washed with water in amount of l per kg of phosphogypsum to obtain washed phosphogypsum and washing sulphuric acid solution
Get PriceThe solution that has been successfully carried out is firstly by modifying the phosphogypsum washing system specifically on its filter by substituting low pH water to a higher pH for washing which generally functions to dissolve the water soluble P 2 O 5 on phosphogypsum
Get PricePhosphogypsum a waste product from manufacturing fertilizer emits radon a radioactive gas It also contains the radioactive elements uranium thorium and radium Phosphate rock mining is the fifth largest mining industry in the United States in terms of the amount of material mined The phosphate industry is concentrated in the southeastern
Get PriceThis set of phosphogypsum washing and drying equipment adopts the sieving washing and grading process flow that is the phosphogypsum is first sieved to remove large particles larger than 25 mm and then added to the grinding tank to grind into a slurry with water and the slurry is removed by trimming and screening
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Get PriceIn the art there are a lot of methods for processing or direct use of waste phosphogypsum For example there is known a method where phosphogypsum is washed with a water solution of citric acid in concentration of 4 5% to obtain gypsum for construction Another method to directly use phosphogypsum is to add it to cement in a quantity of 3% to 4%
Get PricePhosphogypsum is a waste by product from the processing of phosphate rock in plants producing phosphoric acid and phosphate fertilizers such as superphosphate
Get PriceThe comparison of the developed phosphogypsum processing method with well known national and foreign analogues showed that its cost efficiency is 2 3 times higher the area necessary for the plant
Get PricePhosphogypsum is a by product of the phosphates industry Produced in significant quantities the material is considered a waste in the US due to radioactivity where the primary means of management is storage in stacks
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Get Priceneutralizing or converting acidic phosphogypsum into alkaline material for different applications Methods for purification and treatment of phosphogypsum comprised of washing with water sieving 100 micron sieve neutralizing with calcium hydroxide and calcination 9 Thermal treatment of phosphogypsum are also
Get PriceThis experimental investigation was conducted to research the properties of polypropylene PP fiber reinforced cemented paste backfill CPB The unconfined compressive strength UCS of the fiber reinforced CPB showed a significant improvement with average UCS increase ratios of % % and % at 3 7 and 28 days respectively The macroscopic failure mode and SEM analysis
Get PricePhosphogypsum PG is the main solid waste from the production of ammonium phosphate and phosphoric acid raw materials An industrial plant of phosphate fertilisers produces approximately 4 6 tonnes of PG for every ton of phosphoric acid produced The total amount of PG produced up to 2024 was estimated to be around 6 billion tonnes
Get PriceWeigh g of phosphogypsum into a microwave container and add 15 mL conc HNO 3 65 % Add 30 mg Pb 2 and about 232 U 225 Ra to Bq 209 Po tracer Digest at 120 °C for 15 min and at 150 °C for 25 min at 1000 W
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Get PriceAll four processes generate two special wastes process wastewater and phosphogypsum The phosphogypsum is transferred as a slurry to onsite disposal areas referred to as phosphogypsum stacks These stacks are generally constructed directly on unused or mined out land with little or no prior preparation of the land surface
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